|
|
L-proline + holo-[PigG_prolyl-carrier_protein] + ATP <=> L-prolyl-[PigG_prolyl-carrier_protein] + AMP + diphosphate
|
6.2.1.53
L-proline---[L-prolyl-carrier protein] ligase
|
–
|
| |
MetaCyc:
RXN-15779
|
|
|
|
3-oxo-3-(1H-pyrrol-2-yl)propanoyl-[PigH] + L-serine <=> 4-hydroxy-2,2''-bipyrrole-5-methanol + holo-[PigH_polyketide_synthase/acyl-carrier_protein] + CO2 + H2O
|
4.2.1
|
–
|
| |
MetaCyc:
RXN-15784
|
|
|
|
ATP + 4-methoxy-2,2''-bipyrrole-5-carbaldehyde + 2-Methyl-3-n-amyl-pyrrole <=> ADP + phosphate + prodigiosin + H+
|
6.4.1
|
–
|
| |
KEGG:
R11662
MetaCyc:
RXN-15787
|
|
|
|
S-adenosyl-L-methionine + 4-hydroxy-2,2''-bipyrrole-5-carbaldehyde <=> 4-methoxy-2,2''-bipyrrole-5-carbaldehyde + S-adenosyl-L-homocysteine + H+
|
2.1.1
|
–
|
| |
KEGG:
R11670
MetaCyc:
RXN-15786
|
|
|
|
L-prolyl-[PigG_prolyl-carrier_protein] + oxidized_electron_transfer_flavoprotein + H+ <=> 1H-pyrrole-2-carbonyl-[PigG_prolyl-carrier_protein] + reduced_flavodoxin
|
1.3.8.14
L-prolyl-[peptidyl-carrier protein] dehydrogenase
|
–
|
| |
MetaCyc:
RXN-15780
|
|
|
|
2-Methyl-3-n-amyl-dihydropyrrole + O2 <=> 2-Methyl-3-n-amyl-pyrrole + H2O2 + H+
|
1.4.3
|
–
|
| |
MetaCyc:
RXN-15777
|
|
|
|
(S)-3-acetyloctanal + an_L-amino_acid <=> 2-Methyl-3-n-amyl-dihydropyrrole + a_2-oxo_carboxylate + H2O
|
2.6.1
|
–
|
| |
MetaCyc:
RXN-15778
|
|
|
|
1H-pyrrole-2-carbonyl-[PigG_prolyl-carrier_protein] + holo-[PigJ_acyl-carrier_protein] <=> 1H-pyrrole-2-carbonyl-[PigJ_acyl-carrier_protein] + holo-[PigG_prolyl-carrier_protein]
|
not assigned
|
–
|
| |
MetaCyc:
RXN-15781
|
|
|
|
malonyl-CoA + holo-[PigH_polyketide_synthase/acyl-carrier_protein] <=> malonyl-[PigH] + CoA
|
2.3.1
|
–
|
| |
MetaCyc:
RXN-15783
|
|
|
|
pyruvate + trans-2-octenal + H+ <=> (S)-3-acetyloctanal + CO2
|
2.2.1.12
3-acetyloctanal synthase
|
–
|
| |
BRENDA:
BR51185
KEGG:
R11141
MetaCyc:
RXN-15769
|
|
|
|
4-hydroxy-2,2''-bipyrrole-5-methanol + NADP+ <=> 4-hydroxy-2,2''-bipyrrole-5-carbaldehyde + NADPH + H+
|
1.1.1
|
–
|
| |
KEGG:
R11668
MetaCyc:
RXN-15785
|
|
|
|
1H-pyrrole-2-carbonyl-[PigJ_acyl-carrier_protein] + malonyl-[PigH] + H+ <=> 3-oxo-3-(1H-pyrrol-2-yl)propanoyl-[PigH] + holo-[PigJ_acyl-carrier_protein] + CO2
|
2.3.1
|
–
|
| |
MetaCyc:
RXN-15782
|
|
